Product ID:CITGARD 600 MOTOR OIL, SAE 30, 22-630
MSDS Date:10/12/1994
FSC:9150
NIIN:00N073864
MSDS Number: CCPVZ

CITGO PETROLEUM CORP

TULSA, OK 74102
US

Emergency Phone: 918-495-4700;800-424-9300(CHEMTREC)

Info Phone: 918-495-5933

Cage: 1JW40

CITIES SERVICE CO

300 TULSA, OK 74102 US

Telephone: 918-561-5165

Cage: 12518

REFINED PETROLEUM OILS (CONSISTING OF INGS 2 - 7).

Fraction By Weight: >75%

OSHA PEL 5 MG/M3 (OIL MIST)

ACGIH TLV: 5 MG/M3 (OIL MIST)

MINERAL OIL, PETROLEUM DISTILLATES, SOLVENT-REFINED

CAS: 64741-88-4

RTECS: PY8040501

OSHA PEL N/K

ACGIH TLV: N/K

MINERAL OIL, PETROLEUM DISTILLATES, SOLVENT-REFINED

CAS: 64741-89-5

RTECS: PY8041501

OSHA PEL N/K

ACGIH TLV: N/K

SOLVENT DEWAXED RESIDUAL OIL (PETROLEUM)

CAS: 64742-62-7

OSHA PEL N/K

ACGIH TLV: N/K

HIGHLY REFINED BASE OIL

CAS: 72623-87-1

OSHA PEL N/K

ACGIH TLV: N/K

SOLVENT REFINED HYDROTREATED RESIDUAL OIL

CAS: 64742-57-0

OSHA PEL N/K

ACGIH TLV: N/K

MINERAL OIL

CAS: 72623-83-7

OSHA PEL N/K

ACGIH TLV: N/K

ANTI-OXIDANT, ANTI-WEAR, DISPERSANT; (DETERGENT INHIBITOR

Fraction By Weight: <20%

OSHA PEL N/K

ACGIH TLV: N/K

PHOSPHORODITHIOIC ACID, DIALKYL ESTER, ZINC SALT; (ZINC

RTECS: TD5550000

Fraction By Weight: <2%

OSHA PEL N/K

ACGIH TLV: N/K

POUR DEPRESSANT

Fraction By Weight: <0.1%

OSHA PEL N/K

ACGIH TLV: N/K

AREA. RPT SPILLS AS REQD TO APPROP AUTHS. UNDER

RTECS: 9999999ZZ

OF CRUDE OIL & PETRO PRODS IN ANY KIND/FORM TO SURF

RTECS: 9999999ZZ

RULES & REGULATIONS. RCRA EMERGENCY HOTLINE

RTECS: 9999999ZZ

REFER TO

RTECS: 9999999ZZ

EXTENDED, DIRECT CONTACT IS EXPECTED. AVOID

RTECS: 9999999ZZ

MANDATED STANDARDS. RESPONSIBLE INDIVIDUALS SHOULD

RTECS: 9999999ZZ

LD50 LC50 Mixture:SEE INGREDIENT 1.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:SLIGHTLY TOX. APPROX LETHAL DOSE FOR
150 LB HUMAN ADULT IS ABOUT 1 QUART. ACUTE:INHAL:LOW RISK AT
AMBIENT TEMPS. MISTS/FUMES MAY CAUSE DIZZ, HDCH, NAUS, RESP
IRRIT/CHEM PNEUM. MISTS ABOVE TLV MAY CAUS E CHEM PNEUM. DERMAL
CONT:MILD IRRIT. EYE CONT:MAY BE MILDLY IRRIT. INGEST:LOW TOX. ON
INGEST OF LG (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:QTYS, SLIGHT GI DISCOMFORT, DIARR &
HDCH MAY OCCUR. SM DOSES MAY PRDCE IRRIT & DIARR.
INJECTION:SUBCUTANEOUS/INTRAMUSCULAR INJECTION MAY CAUSE IRRIT,
ERYTHEMA, EDEMA. CHRONIC:DERMAL, PRLNG & RPTD EXPOS MAY CAUSE
DRYING, CRACKING (DERM)/FOLLICULITIS. CONTINUOUS CONT W/USED OIL
HAS CAUSED SKIN CANCER IN (SUPDAT)
Medical Cond Aggravated by Exposure:NONE.

First Aid:INHAL:REMOVE FROM EXPOS TO INCIDENTAL FUMES & PROVIDE RESP
SUPPORT IF NEC. SEEK MED AID. SKIN:WASH W/SOAP & WATER. DO NOT WEAR
HEAVILY CONTAM CLTHG BEFORE LAUNDERING. EYES:FLUSH W/LG VOLS OF
WATER FOR AT LST 15 MINS. SEE MD IF ANY COMPLICATIONS ARISE.
INGEST:INDUCE VOMIT & SEEK MED AID. INJECTION:SEEK MED AID IMMED.
SUBCUTANEOUS INJECTION IS MED EMER. NOTES TO MD:FOLLOWING INGEST,
AT (SUPP DATA)

Flash Point Method:PMCC
Flash Point:388F,198C
Extinguishing Media:CO*2, DRY CHEMICAL, FOAM, WATER FOG.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:WATER MAY CAUSE FROTHING.

Spill Release Procedures:REMOVE SOURCES OF HEAT/IGNIT, PROVIDE ADEQ
VENT. SM SPILLS:TAKE UP W/NONCOMBUST ABSORB SUCH AS FULLERS
EARTH/SAND. PLACE INTO CNTNRS FOR LATER DISP. LG SPILLS:CNTN SPILL
IN EARTHEN DIKES FOR LATER REC OVERY. CONTROL IGNIT SOURCES AROUND
SPILL (ING 11)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:KEEP CNTNR TIGHLY CLSD & AWAY FROM
HEAT & FLAMES. AVOID PRLNG SKIN CONT W/USED MOTOR OILS. EYE & SKIN
IRRITANT. AT HIGH TEMPS, MAY EVOLVE H*2S.
Other Precautions:EMPTY CNTNRS MAY CNTN PROD RESIDUE WHICH COULD INCL
FLAMM/EXPLO VAPS. CONSULT APPROP FED, STATE & LOC AUTHS BEFORE
REUSING, RECONDITIONING, RECLAIMING, RECYCLING/DISP OF EMPTY CNTNRS
&/OR WASTE RESIDU ES OF THIS PROD. PROT MEASURES (ING 14)

Respiratory Protection:IF HIGH VAPOR CONCENTRATION IS EXPECTED, USE
NIOSH APPROVED RESPIRATOR FOR ORGANIC VAPORS.
Ventilation:USE IN WELL VENTILATED AREA. IN CONFINED SPACE, MECH VENT
MAY BE REQD TO KEEP LEVELS OF CERTAIN COMPONENTS BELOW(ING 16)
Protective Gloves:OIL IMPERVIOUS GLOVES.
Eye Protection:ANSI APPROVED CHEM WORKERS GOGGS .
Other Protective Equipment:ANSI APPROVED EYE WASH FOUNTAIN & DELUGE
SHOWER . WEAR BODY-COVERING WORK CLOTHES TO AVOID PRLNG/RPTD
EXPOSURE.
Work Hygienic Practices:REMOVE & LAUNDER SOILED WORK CLOTHES BEFORE
REUSE. AFTER DRAINING OIL, WASH EXPOSED SKIN THOROUGHLY W/SOAP &
WATER.
Supplemental Safety and Health
VP:7X10-5 @ 25C. EFTS OF OVEREXP:LAB ANIMALS. FIRST AID PROC:SAYBOLT
VISCOSITY OF APPROX 540 @ 100F, RISK OF ASPIR INTO LUNGS IS
PRACTICALLY ZERO. FOR INGEST OF LG QTYS, EMESIS/LAVAGE MAY BE
CONSIDERE D. SUBCUTANEOUS INJECTION REQS PROMPT SURGICAL
DEBRIDEMENT. IF NOT FAMILIAR W/TECHNIQUE, SEEK SKILLED ADVICE.

Boiling Pt:B.P. Text:685F,363C
Vapor Pres:SUPP DATA
Vapor Density:>1
Spec Gravity:0.89 (H*2O=1)
Evaporation Rate & Reference:<1 (BUTYL ACETATE=1)
Solubility in Water:NEGLIGIBLE
Appearance and Odor:AMBER LIQUID; MILD PETROLEUM ODOR.
Percent Volatiles by Volume:NEGLIG

Stability Indicator/Materials to Avoid:YES
STRONG OXIDANTS, STRONG ACIDS, CAUSTICS.
Stability Condition to Avoid:NONE.
Hazardous Decomposition Products:CO*2, (CO UNDER INCOMPLETE
COMBUSTION), TRACES OF OXIDES OF S, P & ZN. AT HIGH TEMPERATURES,
MAY EVOLVE H*2S.

Waste Disposal Methods:DISP MUST BE I/A/W FED, STATE & LOC REGS . IT IS
RESPONSIBILITY OF USER TO DETERMINE IF MATL IS HAZ WASTE AT TIME OF
DISP. CHECK BEFORE DISP TO BE SURE YOU ARE IN COMPLIANCE W/ALL
APPLIC LAWS & REGS. TREAT USED OIL ACCORDING TO CURRENT (ING 13)

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particular situation.